What country produces the most palm oil

For oil created from the palm kernel, rather than the palm fruit, see Palm kernel oil.

Palm oil is an edible vegetable oil derived from the mesocarp (reddish pulp) of the fruit of the oil palms.[1] The oil is used in food manufacturing, in beauty products, and as biofuel. Palm oil accounted for about 33% of global oils produced from oil crops in 2014.[2] Palm oils are easier to stabilize and maintain quality of flavor and consistency in processed foods, so are frequently favored by food manufacturers.[3] On average globally, humans consumed 7.7 kg (17 lb) of palm oil per person in 2015.[4] Demand has also increased for other uses, such as cosmetics and biofuels, creating more demand on the supply encouraging the growth of palm oil plantations in tropical countries.

Palm oil block showing the lighter color that results from boiling

The use of palm oil has attracted the concern of environmental groups due to deforestation in the tropics where palms are grown, and has been cited as a factor in social problems due to allegations of human rights violations among growers.[5] An industry group formed in 2004 to create more sustainable and ethical palm oil, through the Roundtable on Sustainable Palm Oil. However, very little palm oil is certified through the organization, and some groups have criticized it as greenwashing.[6] In 2018, a report by the International Union for Conservation of Nature acknowledged that palm oil is much more efficient than other oils in terms of land and water usage, however deforestation causes more biodiversity loss than switching to other oils.[7]

The biggest producers of palm oil are Indonesia, Malaysia, Thailand and Nigeria. During the 2022 food crises instigated by the Russian invasion of Ukraine and crop failures in other parts of the world due to extreme weather caused by climate change, the Indonesian government banned exports of palm oil.[8] This combined with a reduced harvest in Malaysia greatly increased global prices, while reducing availability causing ripple effects in the global supply chain.[8] On 23 May 2022, the Indonesian government reopened trading hoping to balance supplies.[9]

 

Oil palms (Elaeis guineensis)

Humans used oil palms as far back as 5,000 years. In the late 1800s, archaeologists discovered a substance that they concluded was originally palm oil in a tomb at Abydos dating back to 3,000 BCE.[10]

Palm oil from E. guineensis has long been recognized in West and Central African countries, used widely as a cooking oil. European merchants trading with West Africa occasionally purchased palm oil for use as a cooking oil in Europe.

Palm oil became a highly sought-after commodity by British traders for use as an industrial lubricant for machinery during Britain's Industrial Revolution.[11] Palm oil formed the basis of soap products, such as Lever Brothers' (now Unilever) "Sunlight" soap, and the American Palmolive brand.[12]

By around 1870, palm oil constituted the primary export of some West African countries, although this was overtaken by cocoa in the 1880s with the introduction of colonial European cocoa plantations.[13][14]

 

Oil palm fruits on the tree

 

An oil palm stem, weighing about 10 kg (22 lb), with some of its fruits picked

Palm oil is naturally reddish in color because of a high beta-carotene content. It is not to be confused with palm kernel oil derived from the kernel of the same fruit[15] or coconut oil derived from the kernel of the coconut palm (Cocos nucifera). The differences are in color (raw palm kernel oil lacks carotenoids and is not red), and in saturated fat content: palm mesocarp oil is 49% saturated, while palm kernel oil and coconut oil are 81% and 86% saturated fats, respectively. However, crude red palm oil that has been refined, neutralized, bleached and deodorized, a common commodity called RBD (refined, bleached, and deodorized) palm oil, does not contain carotenoids.[16] Many industrial food applications of palm oil use fractionated components of palm oil (often listed as "modified palm oil") whose saturation levels can reach 90%;[17] these "modified" palm oils can become highly saturated, but are not necessarily hydrogenated.

The oil palm produces bunches containing many fruits with the fleshy mesocarp enclosing a kernel that is covered by a very hard shell. The FAO considers palm oil (coming from the pulp) and palm kernels to be primary products. The oil extraction rate from a bunch varies from 17 to 27% for palm oil, and from 4 to 10% for palm kernels.[18]

Along with coconut oil, palm oil is one of the few highly saturated vegetable fats and is semisolid at room temperature.[19] Palm oil is a common cooking ingredient in the tropical belt of Africa, Southeast Asia and parts of Brazil. Its use in the commercial food industry in other parts of the world is widespread because of its lower cost[20] and the high oxidative stability (saturation) of the refined product when used for frying.[21][22] One source reported that humans consumed an average 17 pounds (7.7 kg) of palm oil per person in 2015.[4]

Many processed foods either contain palm oil or various ingredients made from it.[23]

Refining

See also: Cooking oil refinement

After milling, various palm oil products are made using refining processes. First is fractionation, with crystallization and separation processes to obtain solid (palm stearin), and liquid (olein) fractions.[24] Then melting and degumming removes impurities. Then the oil is filtered and bleached. Physical refining[clarification needed] removes smells and coloration to produce "refined, bleached and deodorized palm oil" (RBDPO) and free fatty acids,[clarification needed] which are used in the manufacture of soaps, washing powder and other products. RBDPO is the basic palm oil product sold on the world's commodity markets. Many companies fractionate it further to produce palm oil for cooking oil, or process it into other products.[24]

Red palm oil

Since the mid-1990s, red palm oil has been cold-pressed from the fruit of the oil palm and bottled for use as a cooking oil, in addition to other uses such as being blended into mayonnaise and vegetable oil.[16]

Oil produced from palm fruit is called red palm oil or just palm oil. It is around 50% saturated fat—considerably less than palm kernel oil—and 40% unsaturated fat and 10% polyunsaturated fat. In its unprocessed state, red palm oil has an intense deep red color because of its abundant carotene content. Red palm oil also contains sterols, vitamin E, and carotenoids such as alpha-carotene, beta-carotene, and lycopene.[25]

White palm oil

White palm oil is the result of processing and refining. When refined, the palm oil loses its deep red color. It is extensively used in food manufacture and can be found in a variety of processed foods including peanut butter and chips. It is often labeled as palm shortening and is used as a replacement ingredient for hydrogenated fats in a variety of baked and fried products.

The highly saturated nature of palm oil renders it solid at room temperature in temperate regions, making it a cheap substitute for butter or hydrogenated vegetable oils in uses where solid fat is desirable, such as the making of pastry dough and baked goods. The health concerns related to trans fats in hydrogenated vegetable oils may have contributed to the increasing use of palm oil in the food industry.[26]

Palm oil is sometimes used as a minor ingredient in calf milk replacer.[27][28][citation needed]

Non-food consumer products

Palm oil is pervasively used in personal care and cleaning products, and it provides the foaming agent in nearly every soap, shampoo, or detergent. Around 70% of personal care products including soap, shampoo, makeup, and lotion, contain ingredients derived from palm oil. However, there are more than 200 different names for these palm oil ingredients and only 10% of them include the word “palm".[29]

Biomass and biofuels

Palm oil is used to produce both methyl ester and hydrodeoxygenated biodiesel.[30] Palm oil methyl ester is created through a process called transesterification. Palm oil biodiesel is often blended with other fuels to create palm oil biodiesel blends.[31] Palm oil biodiesel meets the European EN 14214 standard for biodiesels.[30] Hydrodeoxygenated biodiesel is produced by direct hydrogenolysis of the fat into alkanes and propane. The world's largest palm oil biodiesel plant is the €550 million Finnish-operated Neste Oil biodiesel plant in Singapore, which opened in 2011 with a capacity of 800,000 tons per year and produces hydrodeoxygenated NEXBTL biodiesel from palm oil imported from Malaysia and Indonesia.[32][33]

Significant amounts of palm oil exports to Europe are converted to biodiesel (as of early 2018: Indonesia: 40%, Malaysia 30%).[34][35] In 2014, almost half of all the palm oil in Europe was burned as car and truck fuel.[36] As of 2018, one-half of Europe's palm oil imports were used for biodiesel.[37] Use of palm oil as biodiesel generates three times the carbon emissions as using fossil fuel,[38] and, for example, "biodiesel made from Indonesian palm oil makes the global carbon problem worse, not better."[39]

There are pressures for increased oil palm production from Indonesian palm-based biodiesel programs. The biodiesel currently contains a 30:70 palm oil to conventional diesel ratio (known as B30) at the gas pumps. The Indonesian government is aiming to produce 100% palm oil biodiesel (or B100) to transition out of using conventional diesel. The Indonesian government has estimated it would need to establish approximately 15 million hectares of oil palm plantations to meet these future demands.[40]

The organic waste matter that is produced when processing oil palm, including oil palm shells and oil palm fruit bunches, can also be used to produce energy. This waste material can be converted into pellets that can be used as a biofuel.[41] Additionally, palm oil that has been used to fry foods can be converted into methyl esters for biodiesel. The used cooking oil is chemically treated to create a biodiesel similar to petroleum diesel.[42]

In wound care

Although palm oil is applied to wounds for its supposed antimicrobial effects, research does not confirm its effectiveness.[43]

In 2018–2019, world production of palm oil was 73.5 million metric tons (81.0 million short tons).[44] The annual production of palm oil is projected to reach 240 million metric tons (260 million short tons) by 2050.[45] During the 2022 food crises instigated by the Russian invasion of Ukraine and crop failures in other parts of the world due to extreme weather caused by climate change, the Indonesian government banned exports of palm oil.[8] This combined with a reduced harvest in Malaysia greatly increased global prices, while reducing availability.[8]

Indonesia

Main article: Palm oil production in Indonesia

 

A palm oil plantation in Indonesia

Indonesia is the world's largest producer of palm oil, surpassing Malaysia in 2006, producing more than 20.9 million metric tons (23.0 million short tons),[46][47] a number that has since risen to over 34.5 million metric tons (38.0 million short tons) (2016 output).[48][49][50][51] Indonesia expects to double production by the end of 2030.[52] By 2019, this number was 51.8 million metric tons (57.1 million short tons).[53] At the end of 2010, 60% of the output was exported in the form of crude palm oil.[54] FAO data shows production increased by over 400% between 1994 and 2004, to over 8.7 million metric tons (9.6 million short tons).

Malaysia

Main article: Palm oil production in Malaysia

 

A palm oil plantation in Malaysia

 

A satellite image showing deforestation in Malaysian Borneo to allow the plantation of oil palm

Malaysia is the world's second largest producer of palm oil. In 1992, in response to concerns about deforestation, the Government of Malaysia pledged to limit the expansion of palm oil plantations by retaining a minimum of half the nation's land as forest cover.[55][56]

In 2012, the country [57] produced 18.8 million metric tons (20.7 million short tons) of crude palm oil on roughly 5,000,000 hectares (19,000 sq mi) of land.[58][59] Though Indonesia produces more palm oil, Malaysia is the world's largest exporter of palm oil having exported 18 million metric tons (20 million short tons) of palm oil products in 2011. India, China, Pakistan, the European Union and the United States are the primary importers of Malaysian palm oil products.[60] In 2016, palm oil prices jumped to a four-year high days after Trump's election victory in the US.[61]

Nigeria

As of 2018, Nigeria was the third-largest producer, with approximately 2.3 million hectares (5.7 million acres) under cultivation. Until 1934, Nigeria had been the world's largest producer. Both small- and large-scale producers participated in the industry.[62][63]

Thailand

Thailand is the world's third largest producer of crude palm oil, producing approximately 2 million metric tons (2.2 million short tons) per year, or 1.2% of global output. Nearly all of Thai production is consumed locally. Almost 85% of palm plantations and extraction mills are in south Thailand. At year-end 2016, 4.7 to 5.8 million rai (750,000 to 930,000 hectares, 1,900,000 to 2,300,000 acres) were planted in oil palms, employing 300,000 farmers, mostly on small landholdings of 20 rai (3.2 hectares, 7.9 acres). ASEAN as a region accounts for 52.5 million metric tons (57.9 million short tons) of palm oil production, about 85% of the world total and more than 90% of global exports. Indonesia accounts for 52% of world exports. Malaysian exports total 38%. The biggest consumers of palm oil are India, the European Union, and China, with the three consuming nearly 50% of world exports. Thailand's Department of Internal Trade (DIT) usually sets the price of crude palm oil and refined palm oil Thai farmers have a relatively low yield compared to those in Malaysia and Indonesia. Thai palm oil crops yield 4–17% oil compared to around 20% in competing countries. In addition, Indonesian and Malaysian oil palm plantations are 10 times the size of Thai plantations.[64]

Colombia

In 2018, total palm oil production in Colombia reached 1.6 million metric tons (1.8 million short tons), representing some 8% of national agricultural GDP and benefiting mainly smallholders (65% of Colombia's palm oil sector).[65][66] According to a study from the Environmental, Science and Policy, Colombia has the potential to produce sustainable palm oil without causing deforestation.[67] In addition, palm oil and other crops provide a productive alternative for illegal crops, like coca.[68]

Ecuador

Ecuador aims to help palm oil producers switch to sustainable methods and achieve RSPO certification under initiatives to develop greener industries.[69]

Benin

Palm is native to the wetlands of western Africa, and south Benin already hosts many palm plantations. Its 'Agricultural Revival Programme' has identified many thousands of hectares of land as suitable for new oil palm export plantations. In spite of the economic benefits, Non-governmental organisations (NGOs), such as Nature Tropicale, claim biofuels will compete with domestic food production in some existing prime agricultural sites. Other areas comprise peat land, whose drainage would have a deleterious environmental impact. They are also concerned genetically modified plants will be introduced into the region, jeopardizing the current premium paid for their non-GM crops.[70][71]

According to recent article by National Geographic, most palm oil in Benin is still produced by women for domestic use.[72] The FAO additionally states that peasants in Benin practice agroecology.[73] They harvest palm fruit from small farms and the palm oil is mostly used for local consumption.

Cameroon

Cameroon had a production project underway initiated by Herakles Farms in the US.[74] However, the project was halted under the pressure of civil society organizations in Cameroon. Before the project was halted, Herakles left the Roundtable on Sustainable Palm Oil early in negotiations.[75] The project has been controversial due to opposition from villagers and the location of the project in a sensitive region for biodiversity.

Kenya

Kenya's domestic production of edible oils covers about a third of its annual demand, estimated at around 380,000 metric tons (420,000 short tons). The rest is imported at a cost of around US$140 million a year, making edible oil the country's second most important import after petroleum. Since 1993 a new hybrid variety of cold-tolerant, high-yielding oil palm has been promoted by the Food and Agriculture Organization of the United Nations in western Kenya. As well as alleviating the country's deficit of edible oils while providing an important cash crop, it is claimed to have environmental benefits in the region, because it does not compete against food crops or native vegetation and it provides stabilisation for the soil.[76]

Ghana

Ghana has a lot of palm nut species, which may become an important contributor to the agriculture of the region. Although Ghana has multiple palm species, ranging from local palm nuts to other species locally called agric, it was only marketed locally and to neighboring countries. Production is now expanding as major investment funds are purchasing plantations, because Ghana is considered a major growth area for palm oil.

Main article: Social and environmental impact of palm oil

Forests have been cleared in parts of Indonesia and Malaysia to make space for oil-palm monoculture.[77] This has significant impacts on the local ecosystems leading to deforestation and biodiversity loss. For example, these processes have resulted in significant acreage losses of the natural habitat of the three surviving species of orangutan. One species in particular, the Sumatran orangutan, has been listed as critically endangered because of habitat loss due to palm oil cultivation.[78][52]

Social

 

In Borneo, the forest (F), is being replaced by oil palm plantations (G). These changes are irreversible for all practical purposes (H).

In addition to environmental concerns, palm oil development in regions that produce it has also led to significant social conflict. Regions with fast growing palm oil production have experienced significant violations of indigenous land rights, influxes of illegal immigrant labor and labor practices, and other alleged related human rights violations.

The palm oil industry has had both positive and negative impacts on workers, indigenous peoples and residents of palm oil-producing communities. Palm oil production provides employment opportunities, and has been shown to improve infrastructure, social services and reduce poverty.[79][80][81] However, in some cases, oil palm plantations have developed lands without consultation or compensation of the indigenous people inhabiting the land, resulting in social conflict.[82][83][84] The use of illegal immigrants in Malaysia has also raised concerns about working conditions within the palm oil industry.[85][86][87]

Some social initiatives use palm oil cultivation as part of poverty alleviation strategies. Examples include the UN Food and Agriculture Organisation's hybrid oil palm project in Western Kenya, which improves incomes and diets of local populations,[88] and Malaysia's Federal Land Development Authority and Federal Land Consolidation and Rehabilitation Authority, which both support rural development.[89]

Food vs. fuel

Main article: Food vs. fuel

The use of palm oil in the production of biodiesel has led to concerns that the need for fuel is being placed ahead of the need for food, leading to malnutrition in developing nations. This is known as the food versus fuel debate. According to a 2008 report published in the Renewable and Sustainable Energy Reviews, palm oil was determined to be a sustainable source of both food and biofuel, and the production of palm oil biodiesel does not pose a threat to edible palm oil supplies.[90] According to a 2009 study published in the Environmental Science and Policy journal, palm oil biodiesel might increase the demand for palm oil in the future, resulting in the expansion of palm oil production, and therefore an increased supply of food.[91]

Human rights

One report indicated numerous allegations of human rights violations in the production of palm oil in Indonesia and Malaysia, including exposure to hazardous pesticides, child labor, and rape and sexual abuse, and unsafe carrying loads. These incidents may receive no response by the company or police, or are left unreported because victims fear retaliation from their abuser. The chemicals used in the pesticides, such as paraquat and glyphosate, have been linked to diseases such as Parkinson's disease and cancer.[92]

Reports of Indigenous peoples and communities in Indonesia, indicate losing farmland and traditionally significant land due to palm oil industry expansion. In 2017, there were over 650 different land disputes between palm oil plantations and Indigenous land owners.[93] Indigenous communities also expressed concern over the loss of natural resources, such as wild rubber, reed, and adat forests (communal forests).[93] Indigenous communities have made some ground when it comes to land disputes, either through protest or legal means.[93][94]

Other concerns when it comes to Indigenous communities being impacted include lack of government oversight on palm oil plantations, political corruption, or the lacking of enforcement on laws meant to protect Indigenous lands.[95] In countries such as Guatemala, palm oil plantation have significant pressure on local police forces, leading to local police to disregard land claims, going as far as using force to break up protests, and even murdering local leaders.[96]

Environmental

See also: 2015 Southeast Asian haze

While only 5% of the world's vegetable oil farmland is used for palm plantations, palm cultivation produces 38% of the world's total vegetable oil supply.[97] In terms of oil yield, a palm plantation is 10 times more productive than soybean, sunflower or rapeseed cultivation because the palm fruit and kernel both provide usable oil.[97] Palm oil has garnered criticism from environmentalists due to the environmental importance of where it is grown. However, it is indisputably more efficient in comparison to other oil-producing plants. In 2016, it was found that palm oil farms produce around 4.17 metric tons of oil per hectare. Whereas other oils such as sunflower, soybean, or peanut only produce 0.56, 0.39, and 0.16 metric tons respectively per hectare.[98] Palm oil is the most sustainable vegetable oil in terms of yield, requiring one-ninth of land used by other vegetable oil crops.[99] In the future, laboratory-grown microbes might achieve higher yields per unit of land at comparable prices.[100][101]

However, palm oil cultivation has been criticized for its impact on the natural environment,[102][103] including deforestation, loss of natural habitats,[104] and greenhouse gas emissions[105][106] which have threatened critically endangered species, such as the orangutan[107] and Sumatran tiger.[108] Slash-and-burn techniques are still used to create new plantations across palm oil producing countries. From January to September 2019, 857 000 hectares of land was burned in Indonesia; peatlands accounted for more than a quarter of the burned area.[109]

Environmental groups such as Greenpeace and Friends of the Earth oppose the use of palm oil biofuels, claiming that the deforestation caused by oil palm plantations is more damaging for the climate than the benefits gained by switching to biofuel and using the palms as carbon sinks.[110]

A 2018 study by the International Union for Conservation of Nature (IUCN) concluded that palm oil is "here to stay" due to its higher productivity compared with many other vegetable oils. The IUCN maintains that replacing palm oil with other vegetable oils would necessitate greater amounts of agricultural land, negatively affecting biodiversity.[99][111] The IUCN advocates better practices in the palm oil industry, including the prevention of plantations from expanding into forested regions and creating a demand for certified and sustainable palm oil products.[111]

In 2019, the Rainforest Action Network surveyed eight global brands involved in palm oil extraction in the Leuser Ecosystem, and said that none was performing adequately in avoiding “conflict palm oil”.[112] Many of the companies told the Guardian they were working to improve their performance.[113] A WWF scorecard rated only 15 out of 173 companies as performing well.[114]

In 2020 a study by Chain Reaction Research concluded that NDPE (No Deforestation, No Peat, No Exploitation) policies cover 83% of palm oil refineries. NDPE policies are according to the Chain Reaction Research the most effective private mechanism to cut the direct link with deforestation, due to the economic leverage refineries have over palm oil growers.[115]

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According to the Hamburg-based Oil World trade journal,[116] in 2008 global production of oils and fats stood at 160 million tonnes. Palm oil and palm kernel oil were jointly the largest contributor, accounting for 48 million tonnes, or 30% of the total output. Soybean oil came in second with 37 million tonnes (23%). About 38% of the oils and fats produced in the world were shipped across oceans. Of the 60 million tonnes of oils and fats exported around the world, palm oil and palm kernel oil made up close to 60%; Malaysia, with 45% of the market share, dominated the palm oil trade.

Production of palm oil that complies with voluntary sustainability standards is growing at a faster rate than conventional production. Standard-compliant production increased by 110% from 2008 to 2016, while conventional production increased by 2%.[117]

Food label regulations

Previously, palm oil could be listed as "vegetable fat" or "vegetable oil" on food labels in the European Union (EU). From December 2014, food packaging in the EU is no longer allowed to use the generic terms "vegetable fat" or "vegetable oil" in the ingredients list. Food producers are required to list the specific type of vegetable fat used, including palm oil. Vegetable oils and fats can be grouped together in the ingredients list under the term "vegetable oils" or "vegetable fats" but this must be followed by the type of vegetable origin (e.g., palm, sunflower, or rapeseed) and the phrase "in varying proportions".[118]

Supply chain institutions

Consumer Goods Forum

In 2010, the Consumer Goods Forum passed a resolution that its members would reduce deforestation through their palm oil supply to net zero by 2020.[119]

Roundtable on Sustainable Palm Oil (RSPO)

Main article: Roundtable on Sustainable Palm Oil

The Roundtable on Sustainable Palm Oil (RSPO) was established in 2004[120] following concerns raised by non-governmental organizations about environmental impacts resulting from palm oil production. The organization has established international standards for sustainable palm oil production.[121] Products containing Certified Sustainable Palm Oil (CSPO) can carry the RSPO trademark.[122] Members of the RSPO include palm oil producers, environmental groups, and manufacturers who use palm oil in their products.[120][121] In 2014, Indonesia accounted for 40% of global palm oil production and 44% of the total RSPO-certified areas.[123]

The RSPO is applying different types of programmes to supply palm oil to producers.[124]

  • Book and claim: no guarantee that the end product contains certified sustainable palm oil, supports RSPO-certified growers and farmers
  • Identity preserved: the end user is able to trace the palm oil back to a specific single mill and its supply base (plantations)
  • Segregated: this option guarantees that the end product contains certified palm oil
  • Mass balance: the refinery is only allowed to sell the same amount of mass balance palm oil as the amount of certified sustainable palm oil purchased

GreenPalm is one of the retailers executing the book and claim supply chain and trading programme. It guarantees that the palm oil producer is certified by the RSPO. Through GreenPalm the producer can certify a specified amount with the GreenPalm logo. The buyer of the oil is allowed to use the RSPO and the GreenPalm label for sustainable palm oil on their products.[124]

 

Roundtable No 2 (RT2) in Zurich in 2005

After the meeting in 2009, a number of environmental organisations were critical of the scope of the agreements reached.[120] Palm oil growers who produce CSPO have been critical of the organization because, though they have met RSPO standards and assumed the costs associated with certification, the market demand for certified palm oil remains low.[121][122] Low market demand has been attributed to the higher cost of CSPO, leading palm oil buyers to purchase cheaper non-certified palm oil. Palm oil is mostly fungible. In 2011, 12% of palm oil produced was certified "sustainable", though only half of that had the RSPO label.[125] Even with such a low proportion being certified, Greenpeace has argued that confectioners are avoiding responsibilities on sustainable palm oil, because it says that RSPO standards fall short of protecting the environment.[126] Even though deforestation has decreased in RSPO-certified oil palm plantations, peatlands continue to be drained and burned for the creation of new RSPO-certified palm plantations.[123]

 

Left, reddish palm oil made from the pulp of oil palm fruit. Right, clear palm kernel oil made from the kernels

Main article: Fatty acid

Palm oil, like all fats, is composed of fatty acids, esterified with glycerol. Palm oil has an especially high concentration of saturated fat, specifically the 16-carbon saturated fatty acid, palmitic acid, to which it gives its name. Monounsaturated oleic acid is also a major constituent of palm oil. Unrefined palm oil is a significant source of tocotrienol, part of the vitamin E family.[127][128]

The approximate concentration of esterified fatty acids in palm oil is:[129]

Fatty acid content of palm oil (present as triglyceride esters)
Type of fatty acid Fraction
Myristic saturated C14

1.0%
Palmitic saturated C16

43.5%
Stearic saturated C18

4.3%
Oleic monounsaturated C18:1

36.6%
Linoleic polyunsaturated C18:2

9.1%
Other/unknown

5.5%
black: saturated
grey: monounsaturated
blue: polyunsaturated

Carotenes

Red palm oil is rich in carotenes, such as alpha-carotene, beta-carotene and lycopene, which give it a characteristic dark red color.[128][130] However, palm oil that has been refined, bleached and deodorized from crude palm oil (called "RBD palm oil") does not contain carotenes.[16]

Comparison to other vegetable oils

Properties of vegetable oils[131][132] Type Processing
treatment[133] Saturated
fatty acids Monounsaturated
fatty acids Polyunsaturated
fatty acids Smoke point Total[131] Oleic
acid
(ω-9) Total[131] α-Linolenic
acid
(ω-3) Linoleic
acid
(ω-6) ω-6:3
ratio
Avocado[134] 11.6 70.6 52–66[135] 13.5 1 12.5 12.5:1 250 °C (482 °F)[136]
Brazil nut[137] 24.8 32.7 31.3 42.0 0.1 41.9 419:1 208 °C (406 °F)[138]
Canola[139] 7.4 63.3 61.8 28.1 9.1 18.6 2:1 238 °C (460 °F)[138]
Coconut[140] 82.5 6.3 6 1.7 175 °C (347 °F)[138]
Corn[141] 12.9 27.6 27.3 54.7 1 58 58:1 232 °C (450 °F)[142]
Cottonseed[143] 25.9 17.8 19 51.9 1 54 54:1 216 °C (420 °F)[142]
Flaxseed/linseed[144] 9.0 18.4 18 67.8 53 13 0.2:1 107 °C (225 °F)
Grape seed   10.5 14.3 14.3   74.7 74.7 very high 216 °C (421 °F)[145]
Hemp seed[146] 7.0 9.0 9.0 82.0 22.0 54.0 2.5:1 166 °C (330 °F)[147]
Olive[148] 13.8 73.0 71.3 10.5 0.7 9.8 14:1 193 °C (380 °F)[138]
Palm[149] 49.3 37.0 40 9.3 0.2 9.1 45.5:1 235 °C (455 °F)
Peanut[150] 16.2 57.1 55.4 19.9 0.318 19.6 very high 232 °C (450 °F)[142]
Rice bran oil 25 38.4 2.2 34.4[151] 15.6 232 °C (450 °F)[152]
High-oleic safflower oil[153] 7.5 75.2 75.2 12.8 0 12.8 very high 212 °C (414 °F)[138]
Sesame[154] ? 14.2 39.7 39.3 41.7 0.3 41.3 138:1
Soybean[155] partially hydrogenated 14.9 43.0 42.5 37.6 2.6 34.9 13.4:1
Soybean[156] 15.6 22.8 22.6 57.7 7 51 7.3:1 238 °C (460 °F)[142]
Walnut oil[157] unrefined 9.1 22.8 22.2 63.3 10.4 52.9 5:1 160 °C (320 °F)[158]
Sunflower[159] 8.99 63.4 62.9 20.7 0.16 20.5 very high 227 °C (440 °F)[142]
Cottonseed[160] hydrogenated 93.6 1.5 0.6 0.2 0.3 1.5:1
Palm[161] hydrogenated 88.2 5.7 0
The nutritional values are expressed as percent (%) by mass of total fat.

Contributing significant calories as a source of fat, palm oil is a food staple in many cuisines.[162][163][164] On average globally, humans consumed 7.7 kg (17 lb) of palm oil per person in 2015.[4] Although the relationship of palm oil consumption to disease risk has been previously assessed, the quality of the clinical research specifically assessing palm oil effects has been generally poor.[165] Consequently, research has focused on the deleterious effects of palm oil and palmitic acid consumption as sources of saturated fat content in edible oils, leading to conclusions that palm oil and saturated fats should be replaced with polyunsaturated fats in the diet.[166][167]

A 2015 meta-analysis and 2017 advisory from the American Heart Association indicated that palm oil is among foods supplying dietary saturated fat which increases blood levels of LDL cholesterol and increased risk of cardiovascular diseases, leading to recommendations for reduced use or elimination of dietary palm oil in favor of consuming unhydrogenated vegetable oils.[168][169]

Glycidyl fatty acid esters (GE), 3-MCPD and 2-MCPD, are found especially in palm oils and palm fats because of their refining at high temperatures (approx. 200 °C (392 °F)).[170] Since glycidol, the parent compound of GE, is considered genotoxic and carcinogenic, the EFSA didn't set a safe level for GE. According to the chair of the CONTAM (EFSA’s expert Panel on Contaminants in the Food Chain), "The exposure to GE of babies consuming solely infant formula is a particular concern as this is up to ten times what would be considered of low concern for public health".[170] The EFSA's tolerable daily intake (TDI) of 3-MCPD and its fatty acid esters was set to 0.8 micrograms per kilogram of body weight per day (µg/kg bw/day) in 2016 and increased to 2 µg/kg bw/day in 2017, based on evidence linking this substance to organ damage in animal tests and on possible adverse effects on the kidney and on male fertility.[170][171] According to the EFSA, there is not enough data to set a safe level for 2-MCPD.[170]

Palmitic acid

Excessive intake of palmitic acid, which makes up 44% of palm oil, increases blood levels of low-density lipoprotein (LDL) and total cholesterol, and so increases risk of cardiovascular diseases.[166][167][172] Other reviews, the World Health Organization, and the US National Heart, Lung and Blood Institute have encouraged consumers to limit the consumption of palm oil, palmitic acid and foods high in saturated fat.[162][166][172][173]

 

Wikimedia Commons has media related to Palm oil.

  • Coconut oil
  • Palm sugar
  • Tropical agriculture

Zuckerman, Jocelyn C. (2021). Planet Palm: How Palm Oil Ended Up in Everything―and Endangered the World. The New Press. ISBN 978-1620975237.

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  132. ^ "Fats and fatty acids contents per 100 g (click for "more details"). Example: Avocado oil (user can search for other oils)". Nutritiondata.com, Conde Nast for the USDA National Nutrient Database, Standard Release 21. 2014. Retrieved 7 September 2017. Values from Nutritiondata.com (SR 21) may need to be reconciled with most recent release from the USDA SR 28 as of Sept 2017.
  133. ^ "USDA Specifications for Vegetable Oil Margarine Effective August 28, 1996" (PDF).
  134. ^ "Avocado oil, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  135. ^ Feramuz Ozdemir; Ayhan Topuz (May 2003). "Changes in dry matter, oil content and fatty acids composition of avocado during harvesting time and post-harvesting ripening period" (PDF). Elsevier. Retrieved 15 January 2020.
  136. ^ Marie Wong; Cecilia Requejo-Jackman; Allan Woolf (April 2010). "What is unrefined, extra virgin cold-pressed avocado oil?". Aocs.org. The American Oil Chemists’ Society. Retrieved 26 December 2019.
  137. ^ "Brazil nut oil, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  138. ^ a b c d e Katragadda, H. R.; Fullana, A. S.; Sidhu, S.; Carbonell-Barrachina, Á. A. (2010). "Emissions of volatile aldehydes from heated cooking oils". Food Chemistry. 120: 59–65. doi:10.1016/j.foodchem.2009.09.070.
  139. ^ "Canola oil, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  140. ^ "Coconut oil, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  141. ^ "Corn oil, industrial and retail, all purpose salad or cooking, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  142. ^ a b c d e Wolke, Robert L. (16 May 2007). "Where There's Smoke, There's a Fryer". The Washington Post. Retrieved 5 March 2011.
  143. ^ "Cottonseed oil, salad or cooking, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  144. ^ "Linseed/Flaxseed oil, cold pressed, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  145. ^ Garavaglia J, Markoski MM, Oliveira A, Marcadenti A (2016). "Grape Seed Oil Compounds: Biological and Chemical Actions for Health". Nutrition and Metabolic Insights. 9: 59–64. doi:10.4137/NMI.S32910. PMC 4988453. PMID 27559299.
  146. ^ Callaway J, Schwab U, Harvima I, Halonen P, Mykkänen O, Hyvönen P, Järvinen T (April 2005). "Efficacy of dietary hempseed oil in patients with atopic dermatitis". The Journal of Dermatological Treatment. 16 (2): 87–94. doi:10.1080/09546630510035832. PMID 16019622. S2CID 18445488.
  147. ^ "Smoke points of oils" (PDF).
  148. ^ "Olive oil, salad or cooking, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  149. ^ "Palm oil, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  150. ^ "FoodData Central". fdc.nal.usda.gov.
  151. ^ Orthoefer, F. T. (2005). "Chapter 10: Rice Bran Oil". In Shahidi, F. (ed.). Bailey's Industrial Oil and Fat Products. Vol. 2 (6 ed.). John Wiley & Sons, Inc. p. 465. doi:10.1002/047167849X. ISBN 978-0-471-38552-3.
  152. ^ "Rice bran oil". RITO Partnership. Retrieved 22 January 2021.
  153. ^ "Safflower oil, salad or cooking, high oleic, primary commerce, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
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  155. ^ "Soybean oil, salad or cooking, (partially hydrogenated), fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  156. ^ "Soybean oil, salad or cooking, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  157. ^ "Walnut oil, fat composition, 100 g". US National Nutrient Database, United States Department of Agriculture.
  158. ^ "Smoke Point of Oils". Baseline of Health. Jonbarron.org.
  159. ^ "FoodData Central". fdc.nal.usda.gov.
  160. ^ "Cottonseed oil, industrial, fully hydrogenated, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  161. ^ "Palm oil, industrial, fully hydrogenated, filling fat, fat composition, 100 g". US National Nutrient Database, Release 28, United States Department of Agriculture. May 2016. Retrieved 6 September 2017.
  162. ^ a b Diet Nutrition and the Prevention of Chronic Diseases (PDF). World Health Organization (Report). 2003. p. 82,88. Archived from the original (PDF) on 21 September 2012. Retrieved 13 February 2013.
  163. ^ "The other oil spill". The Economist. 24 June 2010. Archived from the original on 9 February 2013. Retrieved 12 February 2013.
  164. ^ Bradsher, Keith (19 January 2008). "A New, Global Oil Quandary: Costly Fuel Means Costly Calories". The New York Times. Archived from the original on 1 January 2015. Retrieved 12 February 2013.
  165. ^ Mancini, A; Imperlini, E; Nigro, E; Montagnese, C; Daniele, A; Orrù, S; Buono, P (2015). "Biological and Nutritional Properties of Palm Oil and Palmitic Acid: Effects on Health". Molecules. 20 (9): 17339–61. doi:10.3390/molecules200917339. PMC 6331788. PMID 26393565.
  166. ^ a b c Sacks FM, Lichtenstein AH, Wu JH, Appel LJ, Creager MA, Kris-Etherton PM, Miller M, Rimm EB, Rudel LL, Robinson JG, Stone NJ, Van Horn LV (2017). "Dietary Fats and Cardiovascular Disease: A Presidential Advisory from the American Heart Association". Circulation. 136 (3): e1–e23. doi:10.1161/CIR.0000000000000510. PMID 28620111. S2CID 367602.
  167. ^ a b Mozaffarian, D; Clarke, R (2009). "Quantitative effects on cardiovascular risk factors and coronary heart disease risk of replacing partially hydrogenated vegetable oils with other fats and oils" (PDF). European Journal of Clinical Nutrition. 63 Suppl 2: S22–33. doi:10.1038/sj.ejcn.1602976. PMID 19424216. S2CID 34725070.
  168. ^ Sun, Ye; Neelakantan, Nithya; Wu, Yi; Lote-Oke, Rashmi; Pan, An; van Dam, Rob M (20 May 2015). "Palm Oil Consumption Increases LDL Cholesterol Compared with Vegetable Oils Low in Saturated Fat in a Meta-Analysis of Clinical Trials". The Journal of Nutrition. 145 (7): 1549–1558. doi:10.3945/jn.115.210575. ISSN 0022-3166. PMID 25995283.
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  170. ^ a b c d "Process contaminants in vegetable oils and foods". European Food Safety Authority. 3 May 2016. Retrieved 21 December 2020.
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  173. ^ Diet, Nutrition and the Prevention of Chronic Diseases, WHO Technical Report Series 916, Report of a Joint WHO/FAO Expert Consultation, World Health Organization, Geneva, 2003, p. 88 (Table 10)

Retrieved from "//en.wikipedia.org/w/index.php?title=Palm_oil&oldid=1103922695"

Page 2

3-MCPD (3-monochloropropane-1,2-diol or 3-chloropropane-1,2-diol) is an organic chemical compound with the formula HOCH2CH(OH)CH2Cl. It is a colorless liquid. It is a versatile multifunctional building block.[1] The compound has attracted attention as the most common member of chemical food contaminants known as chloropropanols.[2] It is suspected to be carcinogenic in humans.

3-MCPD
Names Preferred IUPAC name

3-Chloropropane-1,2-diol

Other names

3-Monochloropropane-1,2-diol; α-Chlorohydrin; Glycerol α-monochlorohydrin; Chlorodeoxyglycerol; 3-Chloro-1,2-propanediol

Identifiers

CAS Number

  • 96-24-2 
    Y

3D model (JSmol)

  • Interactive image

Beilstein Reference

635684 ChEBI

  • CHEBI:18721 
    Y

ChEMBL

  • ChEMBL3185949

ChemSpider

  • 7018 
    Y

ECHA InfoCard 100.002.267
EC Number

  • 202-492-4

Gmelin Reference

68752 KEGG

  • C18676 
    Y

PubChem CID

  • 7290

UNII

  • QGS78A3T6P 
    Y

CompTox Dashboard (EPA)

  • DTXSID4020664

InChI

  • InChI=1S/C3H7ClO2/c4-1-3(6)2-5/h3,5-6H,1-2H2 

    Y

    Key: SSZWWUDQMAHNAQ-UHFFFAOYSA-N 

    Y

  • InChI=1/C3H7ClO2/c4-1-3(6)2-5/h3,5-6H,1-2H2

    Key: SSZWWUDQMAHNAQ-UHFFFAOYAR

SMILES

  • ClCC(O)CO

Properties

Chemical formula

C3H7ClO2Molar mass 110.54 g·mol−1 Appearance Viscous, colorless liquid Density 1.32 g·cm−3Melting point −40 °C (−40 °F; 233 K) Boiling point 213 °C (415 °F; 486 K) Hazards GHS labelling:

Pictograms

Signal word

Danger

Hazard statements

H300, H312, H315, H318, H330, H351, H360, H370, H372

Precautionary statements

P201, P202, P260, P261, P264, P270, P271, P280, P281, P284, P301+P310, P302+P352, P304+P340, P305+P351+P338, P307+P311, P308+P313, P310, P311, P312, P314, P320, P321, P322, P330, P332+P313, P362, P363, P403+P233, P405, P501 Safety data sheet (SDS) External MSDS

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

N verify (what is 
Y
N ?)

Infobox references

It is produced in foods treated at high temperatures with hydrochloric acid to speed up protein hydrolysis. As a byproduct of this process, chloride can react with the glycerol backbone of lipids to produce 3-MCPD. 3-MCPD can also occur in foods that have been in contact with materials containing epichlorohydrin-based wet-strength resins which are used in the production of some tea bags and sausage casings.[3]

In 2009, 3-MCPD was found in some East Asian and Southeast Asian sauces such as oyster sauce, Hoisin sauce, and soy sauce.[4] Using hydrochloric acid is far faster than traditional slow fermentation. A 2013 European Food Safety Authority report indicated margarine, vegetable oils (excluding walnut oil), preserved meats, bread, and fine bakery wares as major sources in Europe.[5]

3-MCPD can also be found in many paper products treated with polyamidoamine-epichlorohydrin wet-strength resins.[6]

The International Agency for Research on Cancer has classified 3-MCPD as Group 2B, "possibly carcinogenic to humans".[7] 3-MCPD is carcinogenic in rodents via a non-genotoxic mechanism.[8] It is able to cross the blood-testis barrier and blood–brain barrier.[9] The oral LD50 of 3-chloro-1,2-propanediol is 152 mg/kg bodyweight in rats.[10]

3-MCPD also has male antifertility effects [10][11] and can be used as a rat chemosterilant.[12]

The joint Food Standards Australia New Zealand (FSANZ) set a limit for 3-MCPD in soy sauce of 0.02 mg/kg, in line with European Commission standards which came into force in the EU in April 2002.

In 2000, a survey of soy sauces and similar products available in the UK was carried out by the Joint Ministry of Agriculture, Fisheries and Food/Department of Health Food Safety and Standards Group (JFSSG) and reported more than half of the samples collected from retail outlets contained various levels of 3-MCPD.[13]

In 2001, the United Kingdom Food Standards Agency (FSA) found in tests of various oyster sauces and soy sauces that 22% of samples contained 3-MCPD at levels considerably higher than those deemed safe by the European Union. About two-thirds of these samples also contained a second chloropropanol called 1,3-dichloropropane-2-ol (1,3-DCP) which experts advise should not be present at any levels in food. Both chemicals have the potential to cause cancer and the Agency recommended that the affected products be withdrawn from shelves and avoided.[14][15]

In 2001, the FSA and Food Standards Australia New Zealand (FSANZ) singled out brands and products imported from Thailand, China, Hong Kong, and Taiwan. Brands named in the British warning include Golden Mountain, King Imperial, Pearl River Bridge, Golden Mark, Kimlan, Golden Swan, Sinsin, Tung Chun, and Wanjasham soy sauce. Knorr soy sauce was also implicated, as well as Uni-President Enterprises Corporation creamy soy sauce from Taiwan, Silver Swan soy sauce from the Philippines, Ta Tun soy bean sauce from Taiwan, Tau Vi Yeu seasoning sauce and Soya bean sauce from Vietnam, Zu Miao Fo Shan soy superior sauce and Mushroom soy sauce from China and Golden Mountain and Lee Kum Kee chicken marinade.[16][17][18] Between 2002 and 2004, relatively high levels of 3-MCPD and other chloropropanols were found in soy sauce and other foods in China.[19]

In 2007, in Vietnam, 3-MCPD was found in toxic levels. In 2004, the HCM City Institute of Hygiene and Public Health found 33 of 41 sample of soy sauce with high rates of 3-MCPD, including six samples with up to 11,000 to 18,000 times more 3-MPCD than permitted, an increase over 23 to 5,644 times in 2001,[20] The newspaper Thanh Nien Daily commented, "Health agencies have known that Vietnamese soy sauce, the country's second most popular sauce after fish sauce, has been chock full of cancer agents since at least 2001."[21]

In March 2008, in Australia, "carcinogens" were found in soy sauces, and Australians were advised to avoid soy sauce.[22]

In November 2008, Britain's Food Standards Agency reported a wide range of household name food products from sliced bread to crackers, beefburgers and cheese with 3-MCPD above safe limits. Relatively high levels of the chemical were found in popular brands such as Mother's Pride, Jacobs crackers, John West, Kraft Dairylea and McVitie's Krackawheat. The same study also found relatively high levels in a range of supermarket own-brands, including Tesco char-grilled beefburgers, Sainsbury's Hot 'n Spicy Chicken Drumsticks and digestive biscuits from Asda. The highest levels of 3-MCPD found in a non- soy sauce product, crackers, was 134 μg per kg. The highest level of 3-MCPD found in soy sauce was 93,000 μg per kg, 700 times higher. The legal limit for 3-MCPD coming in next year[when?] will be 20 μg per kg, but the safety guideline on daily intake is 120 μg for a 60 kg person per day.[citation needed]

In 2016, the occurrence of 3-MCPD in selected paper products (coffee filters, tea bags, disposable paper hot beverage cups, milk paperboard containers, paper towels) sold on the Canadian and German market was reported and the transfer of 3-MCPD from those products to beverages was investigated.[23] Exposure to 3-MCPD from packaging material would likely constitute only a small percentage of overall dietary exposure when compared to the intake of processed oils/fats containing 3-MCPD equivalent (in form of fatty acid esters) which are often present at levels of about 0.2-2 μg/g.

  1. ^ Fernandez-Megia, Eduardo; Correa, Juan; Rodríguez-Meizoso, Irene; Riguera, Ricardo (2006). "A Click Approach to Unprotected Glycodendrimers†". Macromolecules. 39 (6): 2113–2120. Bibcode:2006MaMol..39.2113F. doi:10.1021/ma052448w.
  2. ^ Howard, Philip H.; Muir, Derek C. G. (2010). "Identifying New Persistent and Bioaccumulative Organics Among Chemicals in Commerce". Environmental Science & Technology. 44 (7): 2277–2285. Bibcode:2010EnST...44.2277H. doi:10.1021/es903383a. PMID 20163179.
  3. ^ IFST issues statement on 3-MCPD
  4. ^ "Food Standards Agency - 3-MCPD in soy sauce and related products - Q&As". Archived from the original on 2014-02-22.
  5. ^ European Food Safety Authority (2013). "Analysis of occurrence of 3-monochloropropane-1,2-diol (3-MCPD) in food in Europe in the years 2009-2011 and preliminary exposure assessment". EFSA Journal. 11 (9): 3381. doi:10.2903/j.efsa.2013.3381.
  6. ^ Bodén, Lennart; Lundgren, Michael; Stensiö, Karl-Erland; Gorzynski, Marek (1997-11-14). "Determination of 1,3-dichloro-2-propanol and 3-chloro-1,2-propanediol in papers treated with polyamidoamine-epichlorohydrin wet-strength resins by gas chromatography-mass spectrometry using selective ion monitoring". Journal of Chromatography A. 788 (1): 195–203. doi:10.1016/S0021-9673(97)00711-5.
  7. ^ "List of classifications". International Agency for Research on Cancer. Archived from the original on 2017-06-10. Retrieved 2017-12-19.
  8. ^ Robjohns S, Marshall R, Fellows M, Kowalczyk G (September 2003). "In vivo genotoxicity studies with 3-monochloropropan-1,2-diol". Mutagenesis. 18 (5): 401–4. doi:10.1093/mutage/geg017. PMID 12960406.
  9. ^ Edwards, Elizabeth M.; Jones, A. R.; Waites, G. M. H. (May 1975). "The entry of alpha-chlorohydrin into body fluids of male rats and its effect upon the incorporation of glycerol into lipids". J Reprod Fertil. 43 (2): 225–232. doi:10.1530/jrf.0.0430225. PMID 1127646.
  10. ^ a b Ericsson RJ, Baker VF (March 1970). "Male antifertility compounds: biological properties of U-5897 and U-15,646". Journal of Reproduction and Fertility. 21 (2): 267–73. doi:10.1530/jrf.0.0210267. PMID 5443210. S2CID 32271242.
  11. ^ Samojlik E, Chang MC (April 1970). "Antifertility activity of 3-chloro-1,2-propanediol (U-5897) on male rats". Biology of Reproduction. 2 (2): 299–304. doi:10.1095/biolreprod2.2.299. PMID 5520328.[permanent dead link]
  12. ^ Ericsson RJ (July 1970). "Male antifertility compounds: U-5897 as a rat chemosterilant". Journal of Reproduction and Fertility. 22 (2): 213–22. doi:10.1530/jrf.0.0220213. PMID 5428943.
  13. ^ Macarthur R, Crews C, Davies A, Brereton P, Hough P, Harvey D (November 2000). "3-monochloropropane-1,2-diol (3-MCPD) in soy sauces and similar products available from retail outlets in the UK". Food Additives and Contaminants. 17 (11): 903–6. doi:10.1080/026520300750038072. PMID 11271703. S2CID 45724146.
  14. ^ "Food.gov.uk press release soysauce". Archived from the original on 2010-12-10. Retrieved 2008-10-16.
  15. ^ "Chart with five mentions of affected oyster sauces". Archived from the original on 2009-08-05. Retrieved 2008-10-16.
  16. ^ SOY SAUCE – PUBLIC HEALTH ADVICE Archived 2012-06-09 at the Wayback Machine Food Standards Agency 2001
  17. ^ Junelyn S. de la Rosa (May 2004). "Is your soy sauce safe?". Bar.gov.ph. Archived from the original on 2015-01-15. Retrieved 1 January 2015.
  18. ^ "Tests Show More Soy Sauces are Unsafe". Food Standards Australia New Zealand. 8 October 2001. Archived from the original on 2013-06-24. Retrieved 2013-06-23.
  19. ^ Fu WS, Zhao Y, Zhang G, et al. (August 2007). "Occurrence of chloropropanols in soy sauce and other foods in China between 2002 and 2004". Food Additives and Contaminants. 24 (8): 812–9. doi:10.1080/02652030701246039. PMID 17613068. S2CID 20880307.
  20. ^ Soya sauce stirs worry and discontentment among public Archived May 15, 2010, at the Wayback Machine
  21. ^ Toxic soy sauce, chemical veggies -- food scares hit Vietnam Archived 2010-01-19 at the Wayback Machine
  22. ^ "'Cancer chemical' in soy sauce". Archived from the original on 2008-03-19. Retrieved 2008-11-22.
  23. ^ Becalski, Adam; Zhao, Tony; Breton, Francois; Kuhlmann, Jan (2016-09-01). "2- and 3-Monochloropropanediols in paper products and their transfer to foods". Food Additives & Contaminants: Part A. 33 (9): 1499–1508. doi:10.1080/19440049.2016.1223353. ISSN 1944-0049. PMID 27598381. S2CID 25763740.

  •   Media related to 3-Chloro-1,2-propandiol at Wikimedia Commons
  • Chloropropanols (WHO Food Additive Series 32)

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